| Country | 16 Sep 25 Games | Picks |
|---|---|---|
 | Athletic Bilbao-Arsenal |  |
| PSV Eindhoven-Union Saint Gilloise |  |
| Benfica-Qarabag |  |
| Juventus-Borussia D. |  |
| Real Madrid-Olympique Marseille | |
| Tottenham Hot.-Villarreal |  |
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